| P | W | D | L | F | A | GD | GFA | GAA | Win % |
| 177 | 101 | 36 | 40 | 323 | 162 | 161 | 1.82 | 0.92 | 56.82% |
| Home | Away | |||||||||||
| Season | Rd Reached | P | W | D | L | F | A | W | D | L | F | A |
| 2001-02 | Quarter-Final | 16 | 5 | 2 | 1 | 12 | 5 | 2 | 5 | 1 | 11 | 7 |
| 2002-03 | Group Stage | 6 | 1 | 1 | 1 | 6 | 2 | 1 | 1 | 1 | 6 | 6 |
| 2004-05 | Winners | 15 | 5 | 1 | 1 | 11 | 4 | 4 | 2 | 2 | 9 | 6 |
| 2005-06 | Last 16 | 14 | 3 | 2 | 2 | 8 | 3 | 5 | 1 | 1 | 12 | 4 |
| 2006-07 | Runners Up | 15 | 6 | 0 | 1 | 12 | 3 | 3 | 2 | 3 | 10 | 8 |
| 2007-08 | Semi-Final | 14 | 5 | 1 | 1 | 23 | 5 | 3 | 2 | 2 | 11 | 7 |
| 2008-09 | Quarter-Final | 12 | 4 | 1 | 1 | 11 | 5 | 3 | 3 | 0 | 11 | 7 |
| 2009-10 | Group Stage | 6 | 1 | 0 | 2 | 3 | 4 | 1 | 1 | 1 | 2 | 3 |
| 2014-15 | Group Stage | 6 | 1 | 1 | 1 | 3 | 5 | 0 | 1 | 2 | 2 | 4 |
| 2017-18 | Runners Up | 15 | 5 | 2 | 0 | 24 | 6 | 4 | 2 | 2 | 23 | 13 |
| 2018-19 | Winners | 13 | 5 | 1 | 0 | 14 | 2 | 3 | 0 | 4 | 10 | 10 |
| 2019-20 | Last 16 | 8 | 2 | 1 | 1 | 9 | 8 | 2 | 0 | 2 | 6 | 4 |
| 2020-21 | Quarter-Final | 10 | 3 | 1 | 1 | 5 | 2 | 3 | 1 | 1 | 10 | 4 |
| 2021-22 | Runners Up | 13 | 4 | 1 | 1 | 12 | 6 | 6 | 0 | 1 | 15 | 6 |
| 2022-23 | Last 16 | 8 | 3 | 0 | 0 | 6 | 1 | 2 | 0 | 1 | 11 | 5 |
| 2024-25 | Phase 1 | 6 | 3 | 0 | 0 | 8 | 0 | 3 | 0 | 0 | 5 | 1 |
| Totals | 177 | 56 | 15 | 14 | 167 | 61 | 45 | 21 | 24 | 154 | 95 | |
The Reds have scored 323 goals so far in the UEFA Champions League
ALL Games
Goal 1 : Emile Heskey v FC Haka 8 Aug 2001
Goal 50 : Sami Hyypia v Juventus 5 Apr 2005
Goal 100 : Sami Hyypia v Toulouse 28 Aug 2007
Goal 150 : Fabio Aurelio v Chelsea 14 Apr 2009
Goal 250 : Nicolas Taglifico v Ajax 21 Oct 2020
Last Goal (323) : Mohamed Salah v Girona 10 Dec 2024
Home Goals
Goal 1 : Robbie Fowler v FC Haka 21 Aug 2001
Goal 50 : Peter Crouch v Toulouse 28 Aug 2007
Goal 100 : Philippe Coutinho v Spartak Moscow 06 Dec 2017
Goal 150 : Roberto Firmino v Benfica 05 Apr 2022
Last Goal (169): Cody Gakpo v Real Madrid 27 Nov 2024
Away Goals
Goal 1 : Emile Heskey v FC Haka 8 Aug 2001
Goal 50 : Peter Crouch v Anderlecht 19 Oct 2005
Goal 100 : Virgil van Dijk v Porto 17 Apr 2005
Last Goal (154) : Mohamed Salah v Girona 10 Dec 2024
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